Enhancement Of Characteristics Of A Functionalized Oligophenylene By Acid Hydrolysis Modification

dc.contributor.authorBen Amor, S
dc.contributor.authorBelkhiria, S
dc.contributor.authorHaj Said, A.
dc.contributor.authorRoudesli, S.
dc.date.accessioned2023-09-11T07:26:30Z
dc.date.available2023-09-11T07:26:30Z
dc.date.issued2016
dc.description.abstractNew modified oligophenylene was prepared by acid hydrolysis of a functionalized oligophenylene (OMPA).The latter was obtained by (4-methoxy phenyl) acetonitrile electrochemical oxidation. The resulting modified oligomer (OAC) was characterized by various spectroscopic techniques: NMR, FTIR and UV. The thermal study showed that the modified material exhibited a higher thermal stability compared with OMPA. Further, the optical study revealed that in solution, the emission was blue-shifted when compared with the non-modified oligomer emission and that the optical gap changed from 3.1 eV to 2.75eV. In chloroform solution, photoluminescence was again blue-shifted by 90 nm, which is probably due to an interaction between the oligomer chains.ar
dc.identifier.issn2170-161X
dc.identifier.urihttp://hdl.handle.net/123456789/15503
dc.language.isoenar
dc.publisherOum-El-Bouaghi Universityar
dc.subjectOligophenylenar
dc.subjectOptical gapar
dc.subjectCyclic voltammetryar
dc.subjectPhotoluminescencear
dc.titleEnhancement Of Characteristics Of A Functionalized Oligophenylene By Acid Hydrolysis Modificationar
dc.typeArticlear
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