Effect of acidity and metal content on the activity and product selectivity for n-decane hydroisomerization and hydrocracking over nickel–tungsten supported on silica–alumina catalysts
dc.contributor.author | Rezgui, Y | |
dc.contributor.author | Guemini, M | |
dc.date.accessioned | 2022-04-27T02:57:25Z | |
dc.date.available | 2022-04-27T02:57:25Z | |
dc.date.issued | 2005 | |
dc.description.abstract | Ni–W/silica–alumina based catalysts with different nickel and tungsten concentration (nickel ranging from 12 to 17% and tungsten ranging from 8 to 30%) were prepared by sol–gel method. The BET, temperature-programmed desorption of ammonia (TPDA) and inductively coupled plasma-atomic emission spectroscopy (ICP-AES) techniques were used to characterize the prepared solids. Afterwards, the catalysts were screened for activity and selectivity in the hydroconversion of n-decane. Under the experimental conditions, yields of isomers as well as cracking products were a function of both metal content and amount of acid sites. Up to 15% Ni content, nickel increased isomerization selectivity, afterwards, the catalytic selectivity decreased. Moreover, the higher the amount of medium acid sites present on the catalyst, the higher its activity and its deactivation. | ar |
dc.identifier.uri | http://hdl.handle.net/123456789/12940 | |
dc.language.iso | en | ar |
dc.publisher | ELSEVIER | ar |
dc.subject | Cracking | ar |
dc.subject | Decane | ar |
dc.subject | Dewaxing | ar |
dc.subject | Hydroconversion | ar |
dc.subject | Isomerization | ar |
dc.title | Effect of acidity and metal content on the activity and product selectivity for n-decane hydroisomerization and hydrocracking over nickel–tungsten supported on silica–alumina catalysts | ar |
dc.type | Article | ar |
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